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Tetra-ethyl lead

In petrol engines this additive did at least three things:-

The production of harder metals for valves and valve-seats, a reduction in the compression ratio demanded and substitution with compounds in the fuel that reduce pre-detonation and a reduced tolerance for poisonous waste lead to cessation of its use in the Western countries in the latter part of the 20th century.

wikipedia.org dumped 2003-03-17 with terodump